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EXPLORATION AND MINING GEOLOGY JOURNAL EMG Volcanogenic Massive Sulfide Deposits in China: Setting, Feature, and Style Sedimentary Exhalative Massive Sulfide Deposits in the Proterozoic Langshan - Zhaertai Rift in China Geological Setting and Features of the Ashele Cu-Zn Deposit, Xinjiang, China Massive Sulfide Deposits in the Changning-Menglian Back-arc Belt in Western Yunnan, China: Comparison with Modern Analogues in the Pacific Enrichments of Platinum-group Elements in Hydrogenous, Diagenetic and Hydrothermal Marine Manganese and Iron Deposits Conductive Heat Flow Anomalies Associated with Hydrothermal Sulfide Mounds Hydrothermal Fluid Evolution and Ore-forming Processes of Submarine Hydrothermal Systems in the Okinawa Trough Geochemistry of Shallow Submarine Hydrothermal Fluids from Paleohori Bay, Milos, Aegean Sea Metalliferous Sediments off Milos, Hellenic Volcanic Arc Diffuse-flow Hydrothermal Field in an Oceanic Fracture Zone Setting, Northeast Pacific: Deposit Composition Morphology of the Northeastern Mohns Ridge: Results from SeaMARC II Surveys in the Norwegian-Greenland Sea Study of Particle Fluxes in the Broken Spur Hydrothermal Vent Field (29°N, Mid-Atlantic Ridge) Low-temperature Iron and Manganese Mineral Phases of an Inactive Hydrothermal Mound: TAG Hydrothermal Field, Mid-Atlantic Ridge On the Nature of Lipids in Hydrothermal Formations at the Broken Spur and the Vent Field of the Mid-Atlantic Ridge Mineralogy and Chemistry of Massive Sulfides from the Logatchev Hydrothermal Field (14°459N Mid-Atlantic Ridge)
Volcanogenic Massive Sulfide Deposits in China: Setting, Feature, and Style Abstract — Volcanogenic massive sulfide (VMS) deposits, an important base-metal deposit type in China, occur widely in submarine volcanic districts of variable magmatic affinities. These VMS deposits range in age from Archean to Mesozoic, but most are in Proterozoic and Paleozoic sequences. More than 60% of VMS deposits formed in the Paleozoic, the most important metallogenic eon. Three important Paleozoic VMS-metallogenic provinces include Northern Qilian, Sanjiang and Altai provinces. The Proterozoic constitutes the next important era, but with no VMS deposits in the middle Proterozoic. VMS deposits associated with the Proterozoic volcanic rocks occur around the Yangtze Platform and in the western Kunlun-Qinling. The Triassic is third in importance, with VMS deposits concentrated in the Sanjiang Tethys. The Archean has only one VMS deposit, on the northern margin of the Sino-Korea Platform. Geochemistry of the Paleoproterozoic Metavolcanic Rocks and Relation to Cu-Fe VMS Deposits in Central Yunnan, China Abstract — The metavolcanic rocks of the Dahongshan area have been subjected to both widespread hydrothermal alteration from circulating seawater and to regional metamorphism, such that their mineralogic and chemical compositions have been changed significantly. Studies of immobile elements show that these rocks were originally tholeiitic basalts with geochemical characteristics of T-type MORB formed in a mid-ocean ridge environment. The accompanying Cu-Fe-rich VMS mineralization is in keeping with the original petrology and tectonic setting of these metavolcanic rocks. Regional alteration evident in K-Mg enrichment is related to sericitization and chloritization. Local alteration associated with Cu-Fe mineralization appears to have been accompanied by Si enrichment and Na depletion. P enrichment identifies metasomatism related to Cu-Fe reconcentration in the mineralized zone. © 2001 Canadian Institute of Mining, Metallurgy and Petroleum. All rights reserved. Sedimentary Exhalative Massive Sulfide Deposits in the Proterozoic Langshan - Zhaertai Rift in China Abstract — There are a number of sedimentary exhalative massive sulfide (SEDEX) deposits in the Proterozoic Langshan-Zhaertai rift at the western segment of the northern margin of the North China platform in China, including more than ten large, medium and small deposits located in a belt of 300 km EW by 50 km to 100 km NS, with large Cu, Pb, Zn, Ag, and S reserves. In several representative SEDEX deposits in the rift, the mineralizing elements are prominently zoned, horizontally or vertically, with Cu decreasing but Pb increasing from west to east, Cu decreasing but Zn increasing from bottom to top, and Zn restricted to the bottom half. The ore-hosting rocks, characterized by a clear manganese halo, have developed a polymetallic mineralization in positive relation with their carbon contents. Their isotopic aspects are: d34S has relatively large positive values, fluctuating between +5‰ and +35‰, compared with Pb isotopic compositions which are less variable, with a model age of 1600 Ma to 1800 Ma, showing that they are mantle-derived. The mineralizing materials were associated undoubtedly with the contemporaneously faulting events in the rift. The deposits owe their origin to seafloor exhalation, with sedimentary rocks as their hosts. © 2001 Canadian Institute of Mining, Metallurgy and Petroleum. All rights reserved. Geological Setting and Features of the Ashele Cu-Zn Deposit, Xinjiang, China Abstract — The Ashele Cu-Zn deposit is a recently discovered volcanogenic massive sulfide deposit in Xinjiang, China, hosted by Lower to Middle Devonian submarine bimodal volcanic rocks. The primary ores of this polygenetic deposit are represented by massive syn-depositional pyrite, chalcopyrite, and sphalerite, and were formed by submarine exhalation. Hydrothermal alteration consists of strong sericitization, chloritization, silicification, and carbonatization of the metavolcanic rocks beneath the massive orebodies. Depletion of Na2O is an obvious chemical change in the hydrothermal halo. Geological and geochemical evidence suggest that the Ashele Cu-Zn massive sulfide deposit was formed by submarine exhalation related to bimodal volcanic rocks, trapped in a rifting basin, then deformed by shearing, and thermally metamorphosed by the intrusion of dacitic porphyry. Sulfur and lead isotopic studies indicate that metals such as copper and zinc may have originated from spilites, but that volatile components, especially sulfur, were derived directly from submarine volcanic magmas. © 2001 Canadian Institute of Mining, Metallurgy and Petroleum. All rights reserved. Massive Sulfide Deposits in the Changning-Menglian Back-arc Belt in Western Yunnan, China: Comparison with Modern Analogues in the Pacific Abstract — The Changning-Menglian metallogenic belt in western Yunnan, China, is characterized by the occurrences of both Pb-Zn-Cu and Cu massive sulfides in Permo-Carboniferous mafic volcanic sequences. These deposits were formed in a back-arc basin at a rifted continental margin in the Paleozoic Tethys Ocean. Pb-Zn-Cu deposits are associated with alkalic basalt, andesite, and lesser felsic volcanic rocks intercalated with limestone, which probably formed along an immature rifting segment on a continental basement. These volcanic rocks are enriched in K, Ti, LREE, and other incompatible elements, and have the attributes of alkalic within-plate basalt. An extensive unit of sulfide-carbonate-silica shale in proximity to massive sulfides contains high values of Mn, As, Mo, W, Sn, Sb, and Hg, and has REE patterns that are similar to the volcanic rocks. This, together with the graded bedding in the footwall volcanic rocks, suggests that the sulfides precipitated in a shallow, unstable, and carbonate-saturated volcanic basin. A stringer zone is traced downward for 500 m below the massive sulfide orebodies. It is characterized by an upper sericite-quartz zone and an extensive lower skarn alteration with enhanced W, Sn, and Bi. Lead isotope data show both continental basement and magmatic sources may have supplied the ore metals. Cu deposit and occurrences are hosted by tholeiitic units that represent the mature spreading segments in the back-arc basin. The tholeiitic lavas have LREE-depleted or flat REE patterns similar to MORB or back-arc mafic lavas. The cupriferous massive sulfides are overlain by an extensive unit of chlorite-magnetite or ochre, suggesting a relatively oxygenated oceanic basin. Ni and less Co mineralization is found in dolomite veins of the stringer zone. Enhanced concentrations of Ni, Co, Au, and As are found in the massive sulfides and in sulfide-rich tuffites. The geological setting and mineralization of the Changning-Menglian belt has similarities with modern back-arc basins such as the Manus Basin in the western Pacific. © 2001 Canadian Institute of Mining, Metallurgy and Petroleum. All rights reserved. Enrichments of Platinum-group Elements in Hydrogenous, Diagenetic and Hydrothermal Marine Manganese and Iron Deposits Abstract — Twenty-seven marine Mn and Fe deposits chosen for their diverse origins have been analyzed for five platinum-group elements (PGE). The PGE display their highest concentrations in hydrogenous Mn crusts and nodules, lesser concentrations in diagenetic nodules and two to three orders of magnitude lower concentrations in hydrothermal Mn and Fe crusts. This difference of behavior reflects the well-known fractionation of Mn and Fe from the other transition elements, rare earth elements (REE) and PGE in hydrothermal Mn and Fe crusts. Pt, Ru, Rh, and Ir show a close geochemical coherence in these deposits and are differentiated from Pd which shows a negative anomaly with respect to the other PGE in hydrogenous and diagenetic Mn deposits. Pd is less depleted than the other PGE and the Pd anomaly much less pronounced in the hydrothermal Mn and Fe crusts relative to the hydrogenous and diagenetic Mn deposits. Conductive Heat Flow Anomalies Associated with Hydrothermal Sulfide Mounds Abstract - Conductive heat flow anomalies associated with hydrothermal sulfide mounds on the seafloor have been studied. Sulfide mounds tend to focus conductive heat flow because sulfide minerals have a greater thermal conductivity than country rock. The topography of the mound above the seafloor, however, leads to a reduction of heat flow, particularly near the center of the mound. Because the focusing effect is constant, whereas the topographic effect decreases with distance away from the center, the focusing effect dominates toward the edges of the mound. The magnitude of these effects depends upon the conductivity contrast and the height/radius aspect ratio of the mound. Conductive heat flow anomalies at sulfide mounds also result from fluid circulation within the edifice. For the active and relict mounds at the TAG hydrothermal field, which have an aspect ratio of approximately 0.3 and a conductivity contrast of 3, the heat flux through the center of the mound should be roughly 70% of the background heat flux. The maximum effect of heat flow focusing is to increase the heat flux by about 30% above background. By comparing these effects with conductive heat flow data at TAG, we find that advective processes dominate conductive heat flow at both the active and relict mounds. Advective circulation can also give rise to much larger lateral and vertical temperature gradients than would result from conduction alone. © 2001 Canadian Institute of Mining, Metallurgy and Petroleum. All rights reserved. Hydrothermal Fluid Evolution and Ore-forming Processes of Submarine Hydrothermal Systems in the Okinawa Trough Abstract — The Okinawa trough is an active back-arc-spreading center in which submarine hydrothermal exhalation (black chimneys) and sulfide mineralization are forming. Fluid inclusion composition in minerals of the hydrothermal feeder zones in the JADE field shows that the hydrothermal systems are extremely gas-rich. There are two independent and co-existing fluids, CO2-hydrocarbon and saline fluids. Microthermometry and Laser Raman Microprobe (LRM) analyses on individual fluid inclusions of the CO2-hydrocarbon type, dominated by CO2 and containing minor CH4, C2H4, C2H6, N2 and H2S, are almost equivalent to the fluid inclusion composition of a natural gas field. The saline fluid is mainly composed of H2O and contains minor Na+ and K+. It is close to a H2O-NaCl, or H2O-NaCl-KCl system, with salinities from 3.7% to 7.5% NaCl eq. Before venting on the seafloor, the fluids experienced immiscible separation. One of the end-member fluids is downward circulating seawater that interacted with sub-seafloor rocks. The other was gas (volatile)-rich fluid derived from a shallow magma chamber. The immiscibility separation of fluids resulted from the decrease of temperature and pressure of the hydrothermal system and continuous input of magmatic volatiles. The saline fluids in this system are discharging to form sulfide chimneys and black smoke. Meanwhile, CO2-rich fluid discharges as CO2 bubbles through hydrate pipes. A large amount of CO2-CH4-H2S gas or fluid in the upper part of the hydrothermal system, and reaction of this gas or fluid with saline fluids, finally enables the accumulation of metal sulfides. © 2001 Canadian Institute of Mining, Metallurgy and Petroleum. All rights reserved. Geochemistry of Shallow Submarine Hydrothermal Fluids from Paleohori Bay, Milos, Aegean Sea Abstract — Shallow submarine hydrothermal fluids from Paleohori Bay off the Greek Island of Milos have been investigated in detail. The extensive gas and warm (max. 93°C) water vents are enriched in major components such as C1-, Na+, Si, Ca2+, Mn, PO43-, NH4+, K+, Sr2+, H2S and CH4 and depleted in Mg2+, O2 and SO42- relative to ambient seawater. Based on zero-Mg calculations, it is deduced that the submarine vent fluids are related to the geothermal reservoir beneath Milos which has a similar chemical composition. Fluid samples from each vent in Paleohori Bay represent a mixture of hydrothermal end-member fluids derived from the upper and deeper geothermal reservoir systems of Milos, a mantle-derived source, a high-chloride fluid resulting from phase separation of geothermal fluids and a steam-heated CO2-rich meteoric water. © 2001 Canadian Institute of Mining, Metallurgy and Petroleum. All rights reserved. Metalliferous Sediments off Milos, Hellenic Volcanic Arc Abstract — Metalliferous precipitates from submarine hydrothermal discharges have been investigated at four inshore locations off Milos in the Hellenic Volcanic Arc. The fine fraction of the sediments shows considerable variability in the concentrations of elements frequently associated with hydrothermal activity. Manganese varies from 30 ppm to 2500 ppm, encompassing the entire range of values found off Santorini also in the Hellenic Arc. Iron occurs in lower concentrations than off Santorini and Yali, while other elements often associated with hydrothermal activity such as Pb, Zn, As, and Cu also show enrichments in sediments from the hydrothermal vent areas. Selective leaching studies have shown that most elements are variably distributed between the different phases of the sediments but with enriched Pb, Zn, and Mn mainly in easily soluble secondary phases. Hydrothermal inputs are strongest at Palaeochori Bay, less at Voudia Bay and lowest at the Airport Springs and Rivari. The weathering of sulfide and possibly other orebodies is also thought to contribute to some of the elements enriched, while background concentrations are largely supplied from detrital sources. © 2001 Canadian Institute of Mining, Metallurgy and Petroleum. All rights reserved. Diffuse-flow Hydrothermal Field in an Oceanic Fracture Zone Setting, Northeast Pacific: Deposit Composition Abstract — This is the first reported occurrence of an active hydrothermal field in an oceanic fracture zone setting. The hydrothermal field occurs in a pull-apart basin within the Blanco Fracture Zone (BFZ), which has four distinct mineral deposit types: (1) barite mounds and chimneys, (2) barite stockwork breccia, (3) silica-barite beds, and (4) silica, barite, and Fe-Mn oxyhydroxide in sediments. All deposit types contain minor amounts of sulfides. In barite stockwork, silica-barite beds, and mineralized sediment, Ba, Pb, Ag, S, Au, Zn, Cu, Hg, Tl, As, Mo, Sb, U, Cd, and Cu are enriched relative to unmineralized rocks and sediments of the BFZ. Fe and Mn are not enriched in the barite stockwork or silica-barite beds, but along with P, Co, and Mg are enriched in the mineralized sediments. Silver contents in deposits of the hydrothermal field range up to 86 ppm, gold to 0.7 ppm, zinc to 3.2%, copper to 0.8%, and barium to 22%. Morphology of the Northeastern Mohns Ridge: Results from SeaMARC II Surveys in the Norwegian-Greenland Sea Abstract — In 1989-1990, the SeaMARC II side-looking sonar (11 to 12 kHz) and swath bathymetric system imaged more than 80 000 km2 of the seafloor in the Norwegian-Greenland Sea and southern Arctic Ocean. One of our main goals was to investigate the highly oblique (115°) junction between the Mohns and Knipovich ridges, and to determine, using new morphotectonic data, whether or not this junction is stable or in a state of readjustment. These findings are presented in this paper. Study of Particle Fluxes in the Broken Spur Hydrothermal Vent Field (29°N, Mid-Atlantic Ridge) Abstract — The flux of sediment matter was determined using sediment traps near a black smoker ("Saracen’s Head," Broken Spur hydrothermal field) and the mineral and chemical compositions of the settled matter were examined. The metallic minerals are represented by Fe sulfides (pyrite and pyrrhotite), and Cu and Zn sulfides are also found in small and equal quantities. The hydrothermal suspended matter contains abiogenic calcite in amounts comparable to that in Ca sulfates. The content of silica and, specifically, of amorphous Si is unusually low. Such correlations between chemical elements and minerals, together with the isotopic compositions of S and C, are characteristic of a relatively young and active stage in the evolution of a hydrothermal system. Sediment traps within and under neutrally buoyant hydrothermal plumes collected biogenic material in addition to hydrothermal components. Microbial chemosynthetic production of organic carbon near the hydrothermal vent is comparable to primary production in the euphotic layer. Fe, Zn, Ca, Si, Ba and P are enriched in particulate matter in comparison to the background. A vast compound plume containing the discharge of multiple hydrothermal vents was found to the south of the Broken Spur hydrothermal field. © 2001 Canadian Institute of Mining, Metallurgy and Petroleum. All rights reserved. Low-temperature Iron and Manganese Mineral Phases of an Inactive Hydrothermal Mound: TAG Hydrothermal Field, Mid-Atlantic Ridge Abstract — Detailed crystal-chemical study of iron and manganese oxides and some other minerals from low-temperature hydrothermal deposits in a newly discovered inactive mound in the TAG hydrothermal field were used to determine the precipitation sequence of mineral phases during low-temperature processes and their post-sedimentary transformations. Particles of primary sedimentary X-ray amorphous proto-ferrihydrite with high silica content were replaced in situ by nontronite, ferrihydrite, or goethite during alteration. Ferrihydrite is the only proto-hematite phase. The transformation of the iron minerals, related to change in the physicochemical environment, is an important characteristic of low-temperature hydrothermal processes. The occurrence of hydrogenetic Fe vernadite and Mn feroxyhyte in the uppermost part of low-temperature deposits and bottom sediments near the base of the mound is evidence for cessation of low-temperature hydrothermal processes. Among the investigated mineral phases, goethite, nontronite, and hematite are stable in reduced sediments only. © 2001 Canadian Institute of Mining, Metallurgy and Petroleum. All rights reserved. On the Nature of Lipids in Hydrothermal Formations at the Broken Spur and the Vent Field of the Mid-Atlantic Ridge Abstract — The lipid component in hydrothermal deposits of the Logachev vent field, at 14°459N of the Mid-Atlantic Ridge (MAR) and Broken Spur vent field, at 29°N of the MAR, was studied. Biochemical, gas chromatographic (GS), and molecular mass methods (GC-MS) research established the mixed nature of the organic matter (OM) including phytoplanktonogenous, chemosynthesized lipids, and lipids of questionable origin. Specific local conditions around the sulfide ores of the black smokers (absence of free oxygen and presence of reduced copper, which prevents OM degradation) facilitate the preservation of biogenic material, including bacteria. The main differences between the lipid compositions of the hydrothermal deposits of these two vent fields relate to the variable nature of hydrothermal circulation systems. Mineralogy and Chemistry of Massive Sulfides from the Logatchev Hydrothermal Field (14°459N Mid-Atlantic Ridge) Abstract — A horizontal mineralogical-geochemical ore zonation with a southeast to northwest trending succession of Cu and Fe (Zn) main zones has been discovered in the Logatchev hydrothermal field (14°459N Mid-Atlantic Ridge). The major minerals are pyrite, chalcopyrite, bornite, isocubanite, digenite and chalcocite. Zn-sulfide, marcasite and covellite are less abundant. Rare minerals are native copper, zincian copper and cobalt pentlandite (first found in oceanic massive sulfides), Cu and Cu-Co-bearing Fe-disulfides. Two groups of the main sulfide assemblages with different copper contents are recognized: Group I comprises assemblages with primary sulfides (isocubanite, chalcopyrite, pyrite and Zn-sulfide; Cu up to 35 wt% in Cu-bearing minerals); Group II contains assemblages with secondary Cu-rich sulfides (bornite, digenite, chalcocite; Cu ~60 wt%) as well as rare minerals (cobalt pentlandite, native copper and zincian copper). The assemblages of Group I formed at a temperature of about 300°C; the sulfur fugacity (log fs2 atm) at 300°C is probably 9.9. Relations between minerals of this group are contradictory, attributed to non-equilibrium environments, and no unified sequence of crystallization of minerals has been determined. Minerals of Group II replace, rim or cross the assemblages of Group I. Group II minerals crystallized in a distinct sequence (cobalt pentlandite-bornite-digenite-chalcocite-native copper), with increasing copper content from the start to the end of the depositional sequence. This may correspond to pH from 7 to 8 near Eh = -0.2 at 250°C. Minerals of this group were generally formed under hypergene alteration processes. Compositions of ore minerals were studied by means of electron microprobe analysis (EMPA) (150 analyses). Narrow composition fields were revealed in all main sulfides, which comprised known experimental data. ZnS contains 6.0 to 28.0 mol.% FeS, which is close to data known for other hydrothermal massive sulfides from the Mid-Atlantic Ridge (MAR). A common admixture in ZnS is Cu (0.16 to 1.32 wt%). Rare grains of unusual anisotropic Fe-disulfides, (Fe0.95Cu0.05)S2 and Cu(Fe,Co)9S20, were found among the ore minerals. © 2001 Canadian Institute of Mining, Metallurgy and Petroleum. All rights reserved. Last updated: |
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