Volume 10, No. 3 (July 2001) - Published April 17, 2003

PAPERS

Environmental Geochemistry of Kimberlite Materials: Diavik Diamonds Project, Lac de Gras, Northwest Territories, Canada
M.J. Baker, D.W. Blowes, M.J. Logsdon and J.L. Jambor

Abstract — Prior to the development of the Diavik Diamonds Project, baseline studies were conducted to determine the geochemical characteristics of four kimberlite orebodies as an aid in the design of both the water-management system and the facilities for containment of processed kimberlite and ore stockpiles. Materials tested included field samples of volcaniclastic and pyroclastic kimberlite, processed kimberlite (i.e., kimberlite ore which had been screened and washed as part of the processing procedure), and sedimentary mudstone (a minor xenolithic unit which was assimilated during kimberlite emplacement). Approximately 200 samples of kimberlite materials were collected as part of the geochemistry program. Test-work included whole-rock chemical analyses, acid-base accounting, kinetic leach tests using columns, and mineralogical analyses. Diavik kimberlite has major oxide and trace-element concentrations consistent with global averages for kimberlite. The mean total-sulfur content of the kimberlite material is 0.22 wt% S, but with a significant range. The kimberlite has an excess of carbonate minerals over sulfide minerals (average CO2 = 4 wt%, present mainly as calcite), and has a mean neutralization potential of 311 kg CaCO3 equivalent/tonne. A reactive form of framboidal pyrite associated specifically with the mudstone xenoliths is the primary source of sulfide-sulfur. Long-term kinetic tests confirmed the preliminary interpretations that were made from the static-test results. Kimberlite and processed kimberlite are net acid-consuming materials that produce alkaline drainages and have low but detectable leaching rates for SO4 and specific trace metals such as Al, Co, Cu, Ni, and Zn. If segregated from the kimberlite, mudstone xenoliths are acid-generating (pH = 3) and produce an effluent with elevated concentrations of SO4, Fe, Al, Cu, Ni, and Zn. The study demonstrates that xenolithic units in Diavik kimberlites have an important effect on the environmental geochemistry of the ore rock. The mineralogy and aqueous geochemistry of the kimberlite materials are such that they may not be suitable for general earthworks or as an alkaline agent and should report to an engineered facility to protect site water quality.
© 2003 Canadian Institute of Mining, Metallurgy and Petroleum. All rights reserved.

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Ammonium Nitrate-Sulfide Reactivity at the Century Zn-Pb-Ag Mine, Northwest Queensland, Australia
Terry J. Briggs and Ian J. Kelso

Abstract — The Century mine in northwest Queensland, Australia, is a major sediment-hosted zinc-lead-silver orebody, located within the western Mount Isa Basin. Stratiform, carbonaceous shale-hosted mineralization is developed within Proterozoic shale and siltstone sequences of the Lawn Hill Formation. CRA Exploration Pty Ltd (CRAE) discovered the Century deposit in 1990 and open pit mine development commenced in 1998 under the ownership of Pasminco Century Mine Limited (PCML). The deposit contains an identified mineral resource of 105 Mt @ 12.1% Zn + 1.7% Pb + 46 g/t Ag (Broadbent and Waltho, 1998) which is currently being mined at a rate of 5 Mt/y. In December 1998, an exothermic reaction was observed between explosives spilt onto shale drill cuttings from a blasthole. This reaction is referred to as ‘reactive ground’ and has the potential to cause premature detonation of explosives in a charged blasthole with catastrophic consequences. The incident led to a subsequent geological and geochemical assessment of the different rock types at the Century deposit and their potential reactivity with ammonium nitrate-based (AN) explosive products. This assessment was conducted in an attempt to characterize zones safe for blasting with uninhibited AN-based explosive products. A direct result of this study is a set of procedures outlining the use of different AN-based explosives in areas defined as potentially reactive or non-reactive for the different lithologies present. Black shales contained in both the waste and mineralized sequences contain the sulfide mineral pyrite (FeS2), which is thermodynamically unstable with AN contained in commonly used explosives. The potential reactivity of partially weathered pyrite can ultimately result in the decomposition of an AN-based explosive. It was determined that only pyritic black shales showed any potential to react with AN, irrespective of their position in the stratigraphic sequence. Other lithologies present at Century, including Proterozoic sandstone and Cambrian limestone, are classified as non-reactive with AN. This is a geological risk management situation present at the Century mine.
© 2003 Canadian Institute of Mining, Metallurgy and Petroleum. All rights reserved.

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Logistic Regression for Geologically Constrained Mapping of Gold Potential, Baguio District, Philippines
Emmanuel John M. Carranza and Martin Hale

Abstract — An application of logistic regression to mapping of gold potential in the Baguio district of the Philippines is described. Categorical map data such as lithologic units and proximity classes of curvi-linear features, based on spatial association analyses, are quantified systematically and used as independent variables in logistic regression to predict the probability for presence or absence of gold mineralization. Regression experiments to compare between using all independent variables that are associated spatially with the response variable and using only statistically significant independent variables are performed. The results of the regression experiments are similar; however, the use of all independent variables produces slightly optimistic results but better prediction rates for the known gold deposits in the test district. At least 68% of the ‘model’ large-scale gold deposits and at least 76% of the ‘validation’ small-scale gold deposits were predicted correctly. The predicted geologically favorable zones are also similar to delineated geochemically anomalous zones. The technique presented using logistic regression as a data integration tool is effective for geologically constrained technique of mapping mineral potential.
© 2003 Canadian Institute of Mining, Metallurgy and Petroleum. All rights reserved.

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Comments on “The Estimation of Mineralized Veins: A Comparative Study of Direct and Indirect Approaches” by D. Marcotte and A. Boucher
Michel Dagbert

Introduction - In their paper, Marcotte and Boucher (2001) cast some new light on the old problem of 2D estimation of vein-type deposits with thickness and grade of intercepts. Using a theoretical approach, some extensive simulation experiments and the Walker Lake data, they show that the direct approach (interpolation of grade at points on a regular grid) gives better estimates of the true grade at those points than the indirect approach (interpolation of grade x thickness or accumulation and interpolation of thickness) when there is some positive correlation between grade and thickness and that this better performance increases with the correlation of grade and thickness as well as the variability of both variables. We would like to bring some reservations to that conclusion by showing that even if direct point grade estimates are better than indirect ones, it is not necessarily true for block estimates and in particular for the estimated grade of the whole orebody itself.

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Classification and Reporting of Mineral Resources for High-Nugget Effect Gold Vein Deposits
Simon C. Dominy, Patrick R. Stephenson and Alwyn E. Annels

Abstract — The often complex, erratic, and localized nature of gold is a common feature of many vein-style gold deposits. This style of mineralization is often referred to as being nuggety or possessing a high-nugget effect. As a result of these complexities resource estimation is difficult and in general, only Exploration Results can be provided or an Inferred Mineral Resource estimated from surface drilling data alone. Underground development, further drilling, and probably bulk sampling will be required to delineate Indicated and Measured Resources. Tonnages can generally be estimated from diamond drill and development information with a reasonable degree of confidence. Grade is much more difficult to define with confidence because it is commonly highly erratic and discontinuous in nature. The dependency of higher confidence Resource categories on development information may create a Catch 22 situation, with funding for such development often depending on the prior definition of at least Indicated Resources. There are no easy solutions to these challenges posed by high-nugget effect deposits, and it is important when classifying and reporting not to downplay the uncertainties often associated with Mineral Resource and Ore Reserve estimates for such deposits. However, in common with all deposit types, if the principles that underpin the estimation, classification, and reporting procedures are borne in mind and common sense applied, most issues can be satisfactorily resolved. This paper discusses the classification and reporting of Mineral Resources for high-nugget effect gold vein deposits within the framework of the JORC Code (JORC, 1999).
© 2003 Canadian Institute of Mining, Metallurgy and Petroleum. All rights reserved.

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The Estimation of Mineralized Veins: A Comparative Study of Direct and Indirect Approaches
D. Marcotte and A. Boucher

Abstract — The accepted practice for the estimation of thin (2D) vein deposits recommends the use of the grade x thickness service variable (i.e., the accumulation). Grade estimates are obtained indirectly by the estimated accumulation/estimated thickness ratio. This practice stems from the varying support (thickness) problem and the resulting non-additive nature of the grade variable. We compare the actual performance of the direct grade estimation approach used by some practitioners to that of the indirect approach using accumulation. Our simulated and real data indicate that the direct approach is more accurate for point grade estimation where the grade-thickness correlation coefficient is positive (and vice-versa). Moreover, the relative gain of the direct method increases with the (positive) correlation coefficient. This finding contradicts common thinking that the indirect approach should be the preferred method where grade-thickness correlation is strongly positive. Also, for a given positive grade-thickness correlation, the relative gain of the direct method increases with the coefficient of variation of the grade and thickness.
© 2003 Canadian Institute of Mining, Metallurgy and Petroleum. All rights reserved.

Résumé — L’estimation de veines minces (2D) minéralisées est normalement réalisée à l’aide de la variable auxiliaire épaisseur x teneur (i.e., accumulation). Les estimés des teneurs sont alors obtenus indirectement du rapport accumulation estimée/épaisseur estimée. Cette pratique découle du problème du support variable pour la teneur, l’épaisseur de la veine, qui fait que la teneur est alors une variable non-additive. Nous comparons les performances de l’estimation directe de la teneur, utilisée par certains praticiens, à celle de l’approche indirecte. Pour l’estimation ponctuelle des teneurs, nos données simulées et réelles indiquent une meilleure justesse de l’approche directe quand la corrélation teneur-épaisseur est positive (et vice-versa). De plus, le gain relatif de la méthode directe s’accroît avec la valeur de cette corrélation (positive). Ce résultat contredit l’opinion répandue que l’approche indirecte devrait être utilisée en présence de forte corrélation positive de la teneur et de l’épaisseur. Nous montrons également que pour une corrélation positive teneur-épaisseur donnée, le gain de l’approche directe augmente avec les coefficients de variation de l’épaisseur et de la teneur.

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Australian Proterozoic Iron Oxide-Cu-Au Deposits: An Overview with New Metallogenic and Exploration Data from the Cloncurry District, Northwest Queensland
Patrick J. Williams and Peter J. Pollard

Abstract — Enigmatic hydrothermal vein/breccia/replacement Cu-Au deposits with magnetite and/or hematite are well-represented in Australian 1850 Ma to 1500 Ma terrains and associated with different-aged synorogenic intrusions in the Tennant Creek Block (ca. 1850 Ma); the Gawler-Curnamona region (1640 Ma to 1590 Ma); and the Cloncurry district (Mount Isa Eastern Fold Belt, 1540 Ma to 1500 Ma with a possible earlier event at ca. 1600 Ma). No deposits are known to be coeval with various 1780 Ma to 1610 Ma anorogenic intrusions. Deposits are hosted by many different rock-types with varying metamorphic grade including granites and various supracrustal rocks. Depth of mineralization varied from many kilometers in semiductile crust (e.g., Cloncurry deposits) to very shallow (e.g., Olympic Dam). Ore deposition near Cloncurry occurred in brittle-ductile shear zones from geochemically variable and complex, CO2-rich, 300°C to 500°C, high salinity fluids with magmatic stable isotopic signatures. Recently published studies of a giant granitoid-hosted magnetite vein complex at the Lightning Creek prospect (>1000 Mt magnetite) suggest it is a product of internal differentiation and endogenous Fe and Cu-rich hydrous-carbonic fluid phase generation within a quartz monzodiorite-monzogranite intrusion. Coupled with other field relationships, this points to a possible genetic relationship with intermediate (55 to 65 wt% SiO2) members of an alkaline and partly shoshonitic granitoid supersuite which appears to have both mantle and crustal source components from eNd evidence. In constrast, main-phase mineralization at Olympic Dam in the Gawler Craton is distinguished by hematite-phyllosilicate alteration and chalcopyrite-bornite-chalcocite zoning, reflecting fluid mixing in a high level (<250°C) system with a probable large component of meteoric water. Early high-temperature parageneses and fluid inclusions imply that the extensive hematitic breccias overprinted an older magnetite system which may have had similarities with those at Lightning Creek and Ernest Henry in the Cloncurry district. Deposits of this family are inherently difficult to find and evaluate as even within a single district, there is no reliable relationship between the location of ore and any specific combination of geophysical characteristics. Diverse alteration assemblages, geochemistry and physical characteristics suggest the deposits reflect the interaction of multi-sourced fluids with different host rocks in a wide range of geological environments. Recent discoveries and research in the Cloncurry district have extended the range of deposit models available and aid the development of a rudimentary classification in which economic and exploration characteristics can be linked to variations in the mechanisms and environments of ore formation.
© 2003 Canadian Institute of Mining, Metallurgy and Petroleum. All rights reserved.

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